2.2]decane core and defining the geometry of your exocyclic double bond. The activation energies of development from the vinyl-gold intermediates have been calculated and discovered a silyl enol ether having an unprotected indole moiety as an acceptable precursor for the Toste cyclization. This six-step synthesis didn't require any nonstrategic red

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two.two]decane Main and defining the geometry in the exocyclic double bond. The activation energies of formation of your vinyl-gold intermediates were being calculated and exposed a silyl enol ether with an unprotected indole moiety as a suitable precursor for that Toste cyclization. This six-move synthesis didn't include any nonstrategic redox man